Choose 10, choose wisely! Dynamics listed are all the ones I can think of, and some are platonic, others romantic.
Buffy/angel
Buffy/angelus
Buffy/anya
Buffy/cordelia
Buffy/dawn
Buffy/faith
Buffy/giles
Buffy/joyce
Buffy/oz
Buffy/riley
buffy/spike
Buffy/tara
Buffy/willow
Buffy/xander
Buffy/willow/xander
Buffy/willow/xander/giles (core scoobies)
Buffy/dawn/joyce
Willow/angel
Willow/anya
Willow/cordelia
Willow/dawn
Willow/faith
Willow/giles
Willow/oz
Willow/tara
Willow/xander
Xander/angel
Xander/anya
Xander/cordelia
Xander/dawn
Xander/giles
Xander/oz
Xander/riley
Xander/spike
Xander/tara
Giles/angel
Giles/anya
Giles/cordelia
Giles/dawn
Giles/jenny
Giles/joyce
Giles/olivia
Giles/spike
Giles/wesley
Dawn/joyce
Dawn/tara
Faith/angel
Faith/the mayor
Faith/robin
Faith/spike
Faith/xander
Spike/angelus
Spike/anya
Spike/andrew
Spike/dawn
Spike/drusilla
Spike/angelus/drusilla
Spike/riley
Other
Please Specify :
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